Silicon in Organic,
Organometallic, and Polymer Chemistry
Michael
A. Brook
John Wiley & Sons, New York, 2000.
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Abbreviated
Table of Contents:
Part I: The Fundamentals of Silicon
Reactivity: Reactive Intermediates and Reaction
Mechanisms:
Organosilanes: Where to Find Them, What to Call
Them, How to Detect Them. Atomic and
Molecular Properties of Silicon. Silicon-Based
Reactive Intermediates. Extracoordination at
Silicon. Reaction Mechanisms for Nucleophilic
Substitution at Silicon.
Part
II: The Formation and Cleavage of Non-Carbon
Bonds to Silicon: Applications in Organic and
Polymer Chemistry:
Silicon and Transition Metal Chemistry.
Hydrosilanes as Reducing Agents. Replacing H with
Si: Silicon-Based Reagents. Silicones. Siloxanes
Based on T and Q Units. Other Silicon-Containing
Polymers.
Part
III: The Formation and Cleavage of Silicon-Carbon
Bonds: Applications in Organic Synthesis:
Formation of Si-C Bonds: The Synthesis of
Functional Organosilanes. Silicon in a Biological
Environment. Silicon in the Organic World:
Electronic Effects of Silyl Groups.
Rearrangements. Cleavage of Si-C Bonds.
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