Publications (PDFs, Grad students, Undergrads)

Publications by year: 2016 | 2015 | 2014 | 2013 | 2012 | 2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1997 | 1996 | 1990-95 | 1981-89 |


226.     F    Mark Pascoal, Michael A. Brook, Ferdinand Gonzaga, and Laura Zepeda-Velazquez, Thermally controlled silicone functionalization using selective Huisgen reactions, European Polymer Journal 2015, 69, 429–437 (August) DOI: 10.1016/j.eurpolymj.2015.06.026.

225.     F    Madiha F. Khan, Laura Zepeda-Velazquez, and Michael A. Brook,* Tunable, Antibacterial Activity of Silicone Polyether Surfactants, Colloids Surfaces B, Biointerfaces, 2015, 128, 586-593 (August) DOI: 10.1016/j.colsurfb.2015.05.016.

224.    F    Lamees M. Nayef, Madiha Khan and Michael A. Brook,* Human Serum Albumin (HSA) denaturation is particularly facilitated by low molecular weight silicones in oil in water (O/W) emulsions, Colloids Surfaces B, Biointerfaces, 2015, 128, 586–593 (April 1) DOI: 10.1016/j.colsurfb.2015.03.013

223.    F    Paterson, S.M.; Liu, L.; Brook, M.A.: Sheardown, H.* Poly(ethylene glycol)- or silicone-modified hyaluronan for contact lens wetting agent applications. J. Biomed. Mater. Res. Part A 2015, 103, 2602–2610 (August) DOI: 10.1002/jbm.a.35385.

222.    F    Talena Rambarran, Ferdinand Gonzaga, Michael A. Brook,* Frances Lasowski, and Heather Sheardown, Amphiphilic Elastomers from Metal-Free, Click Crosslinking of PEG-Grafted Silicone Surfactants, J. Polym. Chem. A: Polym. Sci. 2015, 53, 1082–1093 (May) DOI: 10.1002/pola.27539.

221.    F    Jianfeng Zhang, Yang Chen, Paul Sewell and Michael A. Brook,* Utilization of softwood lignin as both crosslinker and reinforcing agent in silicone elastomers, Green Chemistry 2015, 17, 1811-1819 (March) DOI: 10.1039/C4GC02409E, plus Correction DOI: 10.1039/c5gc90025e.

220.    F    Ryan C. Chadwick, Darryl Fong, Nicole A. Rice, Michael A. Brook, and Alex Adronov,* Bulk Dispersion of Single-Walled Carbon Nanotubes in Silicones Using Diblock Copolymers, J. Polymer Science A: Polymer Chemistry 2015, 53, 265-273 (January) DOI: 10.1002/pola.27313.


219.  C    Rajendra, Vinodh, Sicard, Clémence, Brennan, John D., Brook, Michael A. Printing silicone-based hydrophobic barriers on paper for microfluidic assays using low-cost office printers, Analyst 2014, 139 (24), 6361-6365 (December) DOI: 10.1039/C4AN01626B.

218.  F    Ryan C. Chadwick, John B. Grande, Michael A. Brook, and Alex Adronov,* Functionalization of Single-Walled Carbon Nanotubes via the Piers-Rubinsztajn Reaction, Macromolecules, 2014, 47 (18), 6527–6530 (September) DOI: 10.1021/ma501297v.

217.  C    John B. Grande, Tomas Urlich, Tara Dickie and Michael A. Brook, Silicone Dendrons from Orthogonal SiH Coupling Reactions, Polymer Chemistry 2014, 5 (23), 6728 - 6739 (August) DOI: 10.1039/c4py00680a.

216.   F     Jianfeng Zhang, Yang Chen and Michael A. Brook,* Reductive degradation of lignin and model compounds by hydrosilanes, ACS Sustainable Chemistry & Engineering, 2014, 2 (8), 1983–1991 (August) DOI: 10.1021/sc500302j.

215.   F    Laura Dodge, Yunqing Chen and Michael A. Brook, Silicone Boronates Reversibly Crosslink Using Lewis Acid:Lewis Base Amine Complexes, Chem. Eur. J. 2014, 20, 9349-9356 (July 21) DOI: 10.1002/chem.201402877.

214.  F    Guidi, Giuliano; Hughes, Timothy C.; Whinton, Marlena; Brook, Michael A.; Sheardown, Heather, The Effect of Silicone Hydrogel Contact Lens Composition on Dexamethasone Release, Journal of Biomaterials Applications, 2014, 29, 222–233 (February) DOI: 10.1177/0885328214521253.

213.  C    Fawcett, A. S.; Brook, M. A., Self-association of pendant coumarin groups converts silicone oils into thermoplastic silicone elastomers, Macromolecules 2014, 47 (5), 1656-1663 (February) DOI:  10.1021/ma402361z.


212.  F.    Vinodh Rajendra and Michael A. Brook, Controlled Formation of Macroporous or Hollow Silica Particles in Non-aqueous Silicone Dispersions, RSC Advances 2013, 3, 22229 – 22238 (September) DOI: 10.1039/C3RA45182H.

211.  F  Jianfeng Zhang and Michael A. Brook, Facile functionalization of PDMS elastomer surfaces using thiol-ene click chemistry, Langmuir 2013, 29 (40), 12432–12442 DOI: 10.1021/la403425d.

210.  F  Ye, L.; Pelton, R.; Brook, M.A.; Filipe, C.; Wang, H.; Brovko, L.; Griffiths, M. Targeted Disinfection of E. Coli via Bioconjugation to Photoreactive TiO2, Bioconjugate Chem. 2013, 24 (3), 448-455 (February) DOI: 10.1021/bc300581t

209.  F  Pelton, R.; Cui, Y.; Zhang, D.; Chen, Y.; Haines, A.; Thompson, K. L.; Armes, S. P.; Brook, M.; Ketelson, H. A Facile Phenylboronate Modification of Silica by a Silaneboronate, Langmuir 2013, 29, 594-598, DOI: 10.1021/la3040837.

208.  C  Brook, M. A.; Dodge, L.; Chen, Y.; Gonzaga, F.; Amarne, H. Sugar complexation to silicone-boronic acids, Chem. Commun., 2013, 49, 1392-1394. DOI:10.1039/C2CC37438B

207.  F  F. Gonzaga, L. Sadowski, T. Rambarran, J. Grande, A. Adronov and M. A. Brook, Highly efficient divergent synthesis of dendrimers via metal-free "click" chemistry, J. Polym. Chem. A.; Polym. Sci., 2013, 51, 1272-1277 DOI: 10.1002/POLA.26511

206.  F   Talena Rambarran, Ferdinand Gonzaga and Michael A. Brook, Multifuntional Amphiphilic Siloxane Architectures Using Sequential, Metal-Free Click Ligations, J. Polym. Chem. A.; Polym. Sci. 2013, 51, 855-864. DOI: 10.1002/pola.26642.

205.  F   Amanda S. Fawcett, John B. Grande and Michael A. Brook Rapid, metal-free room temperature vulcanization produces silicone elastomers, J. Polym. Chem. A: Polym. Sci. 2013, 51, 644-652. DOI:10.1002/pola.26414.

204.  F   So, H.; Fawcett, A.; Sheardown, H.; Brook, M. A. Surface-active copolymer formation stabilizes PEG droplets and bubbles in silicone foams, J. Colloid Interface Sci. 2013, 390, 121-128. DOI: 10.1016/j.jcis.2012.09.017.


203.  F   Michael A. Brook and Mustafa Mohamed, Lewis acid-mediated addition of amino acid-substituted a-allylsilanes to aromatic acetals, Helv. Chim. Acta, 2012, 95, 2660-2671. DOI: 10.1002/hlca.201200533

202.  F  Vanderkooy, A.; Brook, M. A. Polyvinylpyrrolidone Molecular Weight Controls Silica Shell Thickness on Au Nanoparticles with Diglycerylsilane as Precursor, ACS Applied Materials and Interfaces, 2012, 4, 3980–3986, DOI: 10.1021/am300809q

201.  F  Andrea Weeks, David Morrison, Johan Alauzun, Michael A. Brook, Lyndon Jones, Heather Sheardown, Photocrosslinkable HA as an Internal Wetting Agent in Model Conventional and Silicone Hydrogel Contact Lenses, J. Biomed. Mater. Res. Part A, 2012, 100A, 1972-1982,  DOI: 10.1002/mabi.201100001.

200.  F   Farrugia, B. L.; Keddie, D. J.; George, G. A.; Lynam, E. C.; Brook, M. A.; Upton, Z.; Dargaville T. R. An Investigation into the Effect of Amphiphilic Siloxane Oliogmers on Dermal FIbroblasts, J. Biomed. Mater. Res. Part A, 2012, 100A, 1919-1927.

199.  F   Grande, J. B.; Fawcett, A. S.; McLaughlin, A. J.; Gonzaga, F.; Bender, T. P.; Brook, M. A. Anhydrous Formation of Foamed Silicone Elastomers using the Piers-Rubinsztajn Reaction, Polymer 2012, 53, 3135-3142  DOI: 10.1016/m.polymer.2012.05.033.

198.  F   Lu, C.; Mikhail, A. S.; Wang, X.; Brook, M. A.; Allen, C. Hydrogels Containing Core Cross-Linked Block Co-Polymer Micelles, J. Biomater. Sci., Polym. Ed. 2012, 23, 1069-1090 DOI: 10.1163/092050611X575414

197.  F   Rambarran, T.; Gonzaga, F.; Brook, M. A. Generic, metal-free crosslinking and modification of silicone elastomers using click ligation, Macromolecules, 2012, 45, 2276-2285.

196.  F   Kamino, B. A.; Mills, B.; Reali, C.; Gretton, M. J.; Brook, M. A.; Bender, T. P. Liquid Triarylamines: The Scope and Limitations of Piers-Rubinsztajn Conditions for Obtaining Triarylamine-Siloxane Hybrid Materials, J. Org. Chem. 2012, 77, 1663-`1674.

195.  F   Vinodh Rajendra, Ferdinand Gonzaga and Michael A. Brook, Nearly Monodisperse Silica Microparticles Form in Silicone (Pre)elastomer Mixtures, Langmuir, 2012, 28, 1470–1477, DOI: 10.1021/la2035505.

194.  F   Michael J. Gretton, Brett A. Kamino, Michael A. Brook and Timothy P.  Bender, The Use of Piers-Rubinsztajn Conditions for the Placement of Triarylamines Pendant to Silicones, Macromolecules 2012, 45, 723−728.jj

193.  F.  Ferdinand Gonzaga, John B. Grande and Michael A. Brook, Morphology-controlled synthesis of poly(oxyethylene) silicone- or alkyl-silicone surfactants with explicit, atomically-defined branched hydrophobic tails, Chemistry – A European Journal, 2012, 18, 1536–1541, DOI: 10.1002/chem.201103093.

192.  F   Michael A. Brook, Shigui Zhao, Lihua Liu and Yang Chen, Surface Etching of Silicone Elastomers by Depolymerization, Can. J. Chem. 2012, 90, 153-160, 10.1139/v11-145.  Special issue for Bill Chan.


191.  C  Daniel J. Keddie, John B. Grande, Ferdinand Gonzaga, Michael A. Brook and Tim R. Dargaville, Amphiphilic Silicone Architectures via Anaerobic Thiol-Ene Chemistry, Org. Lett., 2011, 13, 6006-6009.

190.  F   Vanderkooy, A.; Chen, Y.; Gonzaga, F.; Brook, M. A. Silica Shell / Gold Core Nanoparticles: Correlating Shell Thickness with the Plasmonic Red Shift upon Aggregation, ACS Applied Materials & Interfaces, 2011, 3, 3942–3947.

189. F    Ng, K. K.; Awad, N.; Brook, M. A.; Holloway, A. C.; Sheardown, H., Local Delivery of Nicotine does not Mitigate Fibrosis but may Lead to Angiogenesis. Journal of Biomaterials Applications 2011, 26 (3), 349-358.

188.  F   Wells, L. A.; Brook, M. A.; Sheardown, H., Generic, Anthracene-Based Hydrogel Crosslinkers for Photo-controllable Drug Delivery. Macromolecular Bioscience 2011, 11 (7), 988-998.

187.  C  Brook, Michael A.; Whinton, Marlena; Gonzaga, F.; Li, Na, Elastomeric Hydrogels by Polymerizing Silicone Microemulsions, Chem. Commun. 2011, 47, 8874 – 8876, DOI: 10.1039/C1CC13331D

186.  F   Wells, L.A., Brook, M.A., Sheardown, H., Photocrosslinkable HA as an Internal Wetting Agent in Model Conventional and Silicone Hydrogel Contact Lenses. Macromolecular Bioscience 2011, 11, 988-998, DOI: 10.1002/mabi.201100001

185.  C  Brett A. Kamino, John B. Grande, Michael A. Brook and Timothy P. Bender, Silicone-Triarylamine Hybrids: Discrete Room Temperature Liquid Triarylamines via the Piers-Rubinsztajn Reaction, Org. Lett. 2011, 13, 154-7.

184.  F   Ferdinand Gonzaga, Renita D’Souza and Michael A. Brook, Oriented crystallization of ultra-thin (2 nm) gold nanoplatelets inside a reactive hydrophobic polymeric matrix, Soft Matter, 2011, 7, 722-729. 


183.  F   Yunping Shao and Michael A. Brook, Structured Metal Films on Silicone Elastomers, J. Mater. Chem. 2010, 20, 8548-8556  DOI: 10.1039/C0JM00824A.

182.  F   John B. Grande, Ferdinand Gonzaga, and Michael A. Brook, Rapid assembly of explicit, functional silicones, Dalton Transactions 2010, 39, 9369-9378 DOI: 10.1039/C0DT00400F

181.  C  John B. Grande, David B. Thompson, Ferdinand Gonzaga and Michael A. Brook, Testing the functional tolerance of the Piers-Rubinsztajn reaction: a new strategy for functional silicones, Chem. Commun., 201046, 4988-4990.

180. F   Babu R. Prasad, Michael A. Brook, Terry Smith, Shigui Zhao, Yang Chen, Heather Sheardown, Renita D’souza and Yuri Rochev, Controlling Cellular Activity by Manipulating Silicone Surface Roughness, Colloids and Surfaces B: Biointerfaces, 2010, 78, 237-242, DOI:10.1016/j.colsurfb.2010.03.006.

179.  F   Andrew S. Mikhail, Jill J. Ranger, Lihua Liu, Ryan Longenecker, David B. Thompson, Heather D. Sheardown,* Michael A. Brook* Rapid and Efficient Assembly of Functional Silicone Surfaces Protected by PEG: Cell Adhesion to Peptide-Modified PDMS, J. Biomat. Sci. 2010, 21, 821–842, DOI:10.1163/156856209X445311.

178.  F   Vinodh Rajendra, Yang Chen, and Michael A. Brook, Structured Hydrophilic Domains in Silicone Elastomers, Polymer Chemistry, 2010, 1, 312-320 DOI: 10.1039/b9py00220k.

177.  F   Johan G. Alauzun, Stuart Young, Renita D'souza, Lina Liu, Michael A. Brook, Heather Sheardown, Biocompatible, Hyaluronic Acid-Modified Silicone Elastomers, Biomaterials 2010, 13, 3471-3478.

176.  F   Amanda S. Fawcett, Helen So and Michael A. Brook, Silicone foams stabilized by surfactants generated in situ from allyl-functionalized PEG, Soft Matter 2010, 6, 1229 – 1237, DOI: 10.1039/b916413h.

175.  F   Rebecca Cademartiri, Hany Anany, Isabelle Gros, Rahul Bhayani, Mansel Griffiths and Michael A. Brook, Immobilization of bacteriophages on modified silica particles, Biomaterials 2010, 31, 1904-1910.



174.  C  Gonzaga, Ferdinand; Yu, Gilbert; Brook, Michael; Polysiloxane elastomers via room temperature, metal free Click chemistry, Macromolecules, 2009, 42, 9220–9224 DOI: 10.1021/ma902026j.

173.  C  Johan G. Alauzun, Heather Sheardown,* Ferdinand Gonzaga, Renita D’Souza and Michael A. Brook* Generic, SN2 Reactive Silicone Surfaces: Facile Routes to New Materials, J. Mater. Chem. 2009, 19, 5033-5038. DOI: 10.1039/b904396a

172.  F   Mustafa Mohamed and Michael A. Brook*, a-(3,5-Bis(silyl)allenyl)amino acid derivatives from the Claisen rearrangement of propargyl glycinates, Collect. Czech. Chem. Commun. 2009, 74, 927-934, Issue in honour of Alfred Bader, invited manuscript.

171   F.  Lucy Ye, Carlos D. M. Filipe, Mojgan Kavoosi, Charles A. Haynes, Robert Pelton, and Michael A. Brook, Immobilization of TiO2 nanoparticles onto cellulose fibers through bioconjugation, J. Mater. Chem., 2009, 19, 2189–2198. DOI=10.1039/b818410k.

170.  F.  Rebecca Cademartiri, Michael A. Brook, Robert Pelton, and John D. Brennan, Macroporous Silica Using a “Sticky” Stöber Process, J. Mater. Chem., 2009, 19, 1583–1592. DOI: 10.1039=b815447c.

169.  F   Weian Zhao, Elodie Pacard, Carole Chaix-Bauvais, Christian Pichot and Michael A. Brook, Covalent Assembly of Silica Nanoparticle Aggregates for Oligonucleotide, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2009, 339, 25-34. DOI 10.1016/j.colsurfa.2009.01.010

168.  C  F. Gonzaga, G. Yu, M. A. Brook, Highly efficient derivatization of polysiloxanes via Click technology,                     Chem. Commun. 2009, 1730 – 1732, DOI:10.1039/B821788B.



167.  F   Klenkler, B. J.; Chen, H.; Chen, Y.; Brook, M. A.; Sheardown, H. A high-density PEG interfacial layer alters the response to an EGF tethered polydimethylsiloxane surface, Journal of Biomaterials Science-Polymer Edition, 2008, 19, 1411-1424.

166.  F   Weian Zhao, M. Monsur Ali, Sergio D. Aguirre, Michael A. Brook* and Yingfu Li,* Paper-based Bioassays Using Gold Nanoparticle Colorimetric Probes, Anal. Chem. 2008, 80, 8431-37. DOI: 10.1021/ac801008q.

165.  F   John H. Kaldis, Michael A. Brook, and Michael J. McGlinchey, Solvent-Mediated Generation of Cobalt Cluster Stabilized Propargyl Cations and Radicals: Allyl Migration versus Peroxide Formation, Chem. Eur. J. 2008, 14, 10074-10084, DOI: 10.1002/chem.200801402

164. F   David B. Thompson, Ferdinand Gonzaga, Amanda S. Fawcett and Michael A. Brook, Hydrolytically stable linkers derived from hydrodiisopropylsilanes, Silicon Chem. 2008, 3, 327-334,  2008 DOI: 10.1007/s11201-008-9035-5

163.  R  Weian Zhao, Michael A. Brook, Yingfu Li, Design of Gold Nanoparticle-Based Colorimetric Biosensing Assays, ChemBioChem 2008, 9, 2363-2371.

162.  F   Paul M. Zelisko, Kulwinder K. Flora, John D. Brennan, and Michael A. Brook, Water-in-Silicone Oil Emulsion Stabilizing Surfactants Formed From Native Albumin and α,ω-Triethoxysilylpropyl-Polydimethylsiloxane, Biomacromolecules, 2008, 9, 2153-2161. DOI: 10.1021/bm800226z

161.  F.  F. Gonzaga, S. Singh, M. A. Brook, Biomimetic Synthesis of Gold Nanocrystals Using a Reducing Amphiphile, Small 2008, 4, 1390-1398. DOI 10.1002/smll.200701163.

160. F   Lucy Ye, Chuanwei Miao, Michael A. Brook, and Robert Pelton, Photo-flocculation of TiO2 Microgel Mixed Suspensions, Langmuir, 2008; 24; 9341-9343.  DOI: 10.1021/la801514t

159.  F   Hong Chen, Liang Wang, Yanxia Zhang, Dan Li, W. Glenn McClung, Michael A. Brook, Heather Sheardown, John L. Brash, Fibrinolytic Poly(dimethylsiloxane) Surfaces, Macromol. Biosci. 2008, 8, 863 – 870.  DOI: 10.1002/mabi.200800014.

158. F   Lawson, G.; Brook, M. A.; Gonzaga, F.; de Silveira, G.; Adronov, A. Au carbon nanotube composites from self-reduction of Au3+ upon poly(ethylene imine) functionalized SWNT thin films, J. Mater. Chem., 2008, 18, 1694–1702. DOI: 10.1039/b715277a.

157. R  Weian Zhao, M. Monsur Ali, Michael A. Brook* and Yingfu Li*. Rolling circle amplification: new applications in nanotechnology and functional nucleic acid-based biodetection. Angew. Chem. Int. Ed., 2008, 47, 6330 – 6337.  DOI: 10.1002/anie.200705982.

156.  F   Weian Zhao, Jeffrey Lam, William Chiuman, Michael A. Brook,* Yingfu Li.* Enzymatic cleavage of nucleic acid on gold nanoparticle: a generic platform for facile biosensors. Small, 2008, 4, 810-816, DOI: 10.1002/smll.200700757.

155.  F   Michael A. Brook, Alison C. Holloway, Kenneth K. Ng, Michael Hrynyk, Carly Moore, and Ryan Lall, Using a Drug to Structure Its Release Matrix and Release Profile, International Journal of Pharmaceutics 2008, 358,121-127; DOI: 10.1016/j.ijpharm.2008.02.029

154.  F   Zhao, Weian; Chiuman, William; Lam, Jeff; McManus, Simon; Chen, Wei; Cui, Yuguo; Brook, Michael; Li, Yingfu DNA Aptamer Folding on Gold Nanoparticle: from Colloid Chemistry to Biosensors, J. Am. Chem. Soc. 2008, 130, 3610-18, DOI: 10.1021/ja710241b

153.  C  David B. Thompson and Michael A. Brook, Rapid Assembly of Complex 3D Siloxane Architectures, J. Am. Chem. Soc. 2008, 130, 32-33. DOI: 10.1021/ja0778491.



152.  F   Michael A. Brook, Hanns – Ulrich Saier, Julia Schnabel, Kaitlin Town, and Michael Maloney, Pretreatment of Liquid Silicone Rubbers (LSR) to Remove Volatile Siloxanes, IECR (Industrial and Engineering Chemical Research) 2007, 46, 8796-8805. DOI: 10.1021/ie061666q.

151.  F   Rebecca Voss, Michael A. Brook,* Jordan Thomson, Yang Chen, Robert H. Pelton and John D. Brennan. Non-destructive horseradish peroxidase immobilization in porous silica nanoparticles, Journal of Materials Chemistry, 2007, 17, 4854 – 4863 DOI:10.1039/B709847B.

150.  C  Weian Zhao, William Chiuman, Jeffrey C. F. Lam, Michael A. Brook,* and Yingfu Li*, Simple and rapid colorimetric enzyme sensing assays using non-crosslinking gold nanoparticle aggregation, Chem. Commun. 2007, 3729-3731.

149.  C  Weian Zhao, Ferdinand Gonzaga, Yingfu Li,* and Michael A. Brook*, Highly Stabilized Nucleotide-capped Small Gold Nanoparticles (d < 5 nm) with Tunable Size, Advanced Materials 2007, 19, 1766-71 http://dx.d

148.  C  Weian Zhao, William Chiuman, Michael A. Brook,* and Yingfu Li*, Simple and Rapid Colorimetric Biosensors Based on DNA Aptamer and Non-crosslinking Gold Nanoparticle Aggregation, ChemBiochem, 2007, 8, 727-731.

147.  F   Lu Ye, Robert Pelton, Michael A. Brook, Biotinylation of TiO2 Nanoparticles and Their Conjugation with Streptavidin, Langmuir, 2007, 23, 5630-5637.

146.  F   Paul M. Zelisko, Aimé Lopez Aguilar, and Michael A. Brook, Delivery of both active enzyme and bleach from water-in-silicone oil (D4) emulsions, Langmuir 2007, 23, 3620-3625. doi=10.1021/la063340s.

145.  F   Sanela Martic, John D. Brennan, Michael A. Brook, Suzanne Ackloo and Noemi Nagy, Towards the development of a covalently tethered MALDI system:  A study of allyl-modified MALDI matrices, Can. J. Chem., 2007, 85, 66-76.

144.  F   Li Gan and Michael A. Brook, Competitive Substitution Reactions at Extracoordinate Silicon During Asymmetric Hydrosilylation, Organometallics 2007, 26, 945-951.



143. F   H. Sheardown, M.A. Brook, H. Chen, Cell Interactions with PDMS Surfaces Modified with Cell Adhesion Peptides using a Generic Method, Materials Science Forum 2006, 539-543, 705-709.

142.  F   Li Gan and Michael A. Brook, Hydrosilylation of Ketones Catalyzed by C2-Symmetric, Proline Derived Complexes, Can. J. Chem. 2006, 84, 1416-1425.

141.  R  Robert Pelton, Xinglian Geng, and Michael Brook, Photocatalytic Paper From Colloidal TiO2  – Fact or Fantasy, Adv. Colloid Interface Sci., 2006, 127, 43-53.

140.  F   Yunyu Yi, Yang Chen, Michael A. Brook and John D. Brennan, Development of Macroporous Titania Monoliths by a Biocompatible Method. Part 2: Enzyme Entrapment Studies, Chem. Mater  2006, 18, 5336-42.

139.  F   Yang Chen, Yunyu Yi, John D. Brennan, Michael A. Brook, Development of Macroporous Titania Monoliths using a Biocompatible Method. Part 1: Material Fabrication and Characterization, Chem. Mater. 2006, 18, 5326-35.

138.  C  Weian Zhao, Yan Gao, Michael A. Brook and Yingfu Li,* Wrapping Single-Walled Carbon Nanotubes with Long Single-Stranded DNA Molecules Produced by Rolling Circle Amplification, Chem. Commun. 2006, 3582-84, DOI: 10.1039/b606518j

137.  L   Brook, Michael A., Comments on Total Platinum Concentration and Platinum Oxidation States in Body Fluids, Tissue, and Explants from Women Exposed to Silicone and Saline Breast Implants by IC-ICPMS, Anal. Chem. 2006, 76, 5609-5611.

136.  F   Liang Liang, James M. Dickson, Jianxiong Jiang, Michael A. Brook, Mass Transfer of Dilute 1,2-Dimethoxyethane Aqueous Solutions During Pervaporation Process, J. Appl. Poly. Sci. 2006, 100, 2075–2084.

135. C  Weian Zhao, Yan Gao, Srinivas A. Kandadai, Michael A. Brook* and Yingfu Li. DNA Polymerization on Gold Nanoparticles via Rolling Circle Amplification: Towards Novel Scaffolds for Three-Dimensional Periodical Nanoassembly, Angew. Chem. Ed. Engl. 2006, 45, 2409 –2413.

134.  F   Elodie Pacard, Michael A. Brook, Amro M. Ragheb, Christian Pichot and Carole Chaix, Elaboration of silica colloid/polymer hybrid support for oligonucleotide synthesis, Colloids Surf. B: Biointerfaces 2006, 47, 176-188.

133.  R  Michael A. Brook, Platinum in Silicone Breast Implants, Biomaterials, 2006, 27, 3274-86 (doi:10.1016/j.biomaterials.2006.01.027)

132.  F   Sui, Xihua; Lin, Tsai-Yin; Tleugabulova, Dina; Chen, Yang; Brook, Michael A.; Brennan, John D.  Monitoring the Distribution of Covalently Tethered Sugar Moieties in Sol-Gel-Based Silica Monoliths with Fluorescence Anisotropy: Implications for Entrapped Enzyme Activity. Chem. Mater. 2006, 18, 887-896.

131.  F   Chen, H., Brook, M. A., Sheardown, H. D., Chen, Y., Klenkler, B. A Generic Bioaffinity Surfaces, Bioconjugate Chemistry 2006, 17, 21-28.



130.  F.  Ragheb, A.M.; Hileman, O.E.; Brook, M. The use of poly(ethylene oxide) for the efficient stabilization of entrapped alpha-chymotrypsin in silicone elastomers: A chemometric study, Biomaterials 2005, 26, 6973-6983, doi:10.1016/j.biomaterials.2005.05.016 

129.  F   Hodgson, Richard J.; Besanger, Travis R.; Brook, Michael A.; Brennan, John D. Inhibitor Screening Using Immobilized Enzyme Reactor Chromatography/Mass Spectrometry. Anal. Chem. 2005, 77, 7512-7519. 

128.  Liang, L.; Dickson, J. M.; Zhu, Z.; Jiang, J.; Brook, M. A., Removal of 1,2-dichloroethane from aqueous solutions with novel composite polydimethylsiloxane pervaporation membranes. J. Appl. Polym. Sci. 2005, 98, 1477-1491.

127.  F   Chen, H.; Chen, Y.; Sheardown, H.; Brook, M. A. Immobilization of heparin on a silicone surface through a PEG spacer, Biomaterials, 2005, 26, 7418-7424.

126.  C  Oliver E. Hileman, Ragheb, A. M.; Brook, M. A. The use of poly(ethylene oxide) for the efficient stabilization of entrapped α-chymotrypsin in silicone elastomers: A chemometric study, Biomaterials 2005, 26, 6973-6983.

125.  F   Yang Chen, Zheng Zhang, Xihua Sui, John D. Brennan and Michael A. Brook, Reduced Shrinkage of Sol-Gel Derived Silica Using Sugar-based Silsesquioxane Precursors, J. Mater. Chem. 2005, 15, 3132 – 3141.

124.  F   Hodgson, Richard J.; Brook, Michael A.; Brennan, John D., Capillary-Scale Monolithic Immunoaffinity Columns for Immunoextraction with In-Line Laser-Induced Fluorescence Detection. Anal. Chem. 2005, 77, 4404-4412

123.  F   Dong, Hanjiang; Brook, Michael A.; Brennan, John D., A New Route to Monolithic Methylsilsesquioxanes: Gelation Behavior of Methyltrimethoxysilane and Morphology of Resulting Methylsilsesquioxanes under One-Step and Two-Step Processing, Chem. Mater. 2005, 17, 2807-2816.

122.  F   Sonya Balduzzi, Michael A. Brook and Michael J. McGlinchey, Diastereoselective Addition of Allyl- and Crotylstannanes to Dicobalt-Complexed Acetylenic Aldehyde, Organometallics 2005, 24, 2617-2627.

121.  F   Kovarik, Peter; Hodgson, Richard J.; Covey, Tom; Brook, Michael A.; Brennan, John D. Capillary-Scale Frontal Affinity Chromatography/MALDI Tandem Mass Spectrometry Using Protein-Doped Monolithic Silica Columns, Anal. Chem. 2005, 77, 3340-3350.

120.  F   Masaaki Amako, Jonathan Schinkel, Michael A. Brook, Michael J. McGlinchey and James F. Britten, Rac/meso Transformations of Disiloxane-bis(1-indenyl)-ansa-ferrocenes: An x-ray Crystallographic and NMR Study, Organometallics, 2005, 24, 1533-1543.

119.  F.  Xihua Sui, Jorge A. Cruz-Aguado, Yang Chen, Zheng Zhang, Michael A. Brook and John D. Brennan, Properties of Human Serum Albumin Entrapped in Sol-Gel-Derived Silica Bearing Covalently Tethered Sugars, Chem. Mater. 2005, 17, 1174-1182.

118.  F     Hong Chen, Michael A. Brook, Yang Chen, and Heather Sheardown, Surface properties of PEO-silicone composites: reducing protein adsorption, J. Biomaterials Sci., Polym. Ed., 2005, 16, 531-548.

117. F   Hong Chen, Zheng Zhang, Yang Chen, Michael A. Brook, Heather Sheardown, Protein Repellant Silicone Surfaces by Covalent Immobilization of Poly(Ethylene Oxide), Biomaterials, 2005, 26, 2391-2399. 

116.  F   Amro Ragheb, Michael A. Brook and Michael Hrynyk, Highly active, lipase silicone composites, Biomaterials, 2005, 26, 1653–1664.

115.  F.  Masaaki Amako, Jonathan Schinkel, Lee Freiburger and Michael A. Brook, Silicone Compatible, Siloxane-Supported Organometallic Compounds and Their Catalytic Activities for the Hydrosilylation of Vinylsilanes and Dienes, J. Chem. Soc., Dalton Trans., 2005, 74 – 81.



114.  F   Michael A. Brook, Yang Chen, Kui Guo, Zheng Zhang and John D. Brennan, Proteins Entrapped in Silica Monoliths Prepared from Glyceroxysilanes, J. Sol. Gel. Sci. Technol. 2004, 31, 343-348.

113.  F   Dina Tleugabulova, Andy M. Duft, Zheng Zhang, Yang Chen, Michael A. Brook and John D. Brennan, Evaluating Formation and Growth Mechanisms of Silica Particles Using Fluorescence Anisotropy Decay Analysis, Langmuir 2004, 20, 5924-5932.

112.  F   Cruz-Aguado, Jorge A.; Chen, Yang; Zhang, Zheng; Brook, Michael A.; Brennan, John D. Entrapment of Src Protein Tyrosine Kinase in Sugar-Modified Silica. Anal. Chem. 2004, 76(14), 4182-4188.

111.  F   Jorge A. Cruz-Aguado, Yang Chen, Zheng Zhang, Nadine H. Elowe, Michael A. Brook and John D. Brennan, Ultrasensitive ATP Detection Using Firefly Luciferase Entrapped in Sugar-Modified Sol-Gel Derived Silica, J. Am. Chem. Soc. 2004, 126, 6878-6879.

110.  F   R. J. Hodgson, Y. Chen, Z. Zhang, D. Tleugabulova, H. Long, X. Zhao, M. Organ, M. A. Brook, J. D. Brennan, Protein-Doped Monolithic Silica Columns for Capillary Liquid Chromatography Prepared by the Sol-Gel Method: Applications to Frontal Affinity Chromatography, Anal. Chem. 2004, 76, 2780-2790.

109. F    Liang, Liang; Dickson, James M.; Jiang, Jianxiong; Brook, Michael A. Pervaporation of 1,2-dimethoxyethane from aqueous solutions by crosslinked oligosilylstyrene-poly(dimethylsiloxane) composite membranes. J. Appl. Poly. Sci. 2004, 92, 2284-2294.

108.  F   Liang, Liang; Dickson, James M.; Jiang, Jianxiong; Brook, Michael A. Effect of low flow rate on pervaporation of 1,2-dichloroethane with novel polydimethylsiloxane composite membranes. J. Membrane Sci. 2004, 231(1-2), 71-79. 

107.  F   Michael A. Brook, Yang Chen, Kui Guo, Zheng Zhang and John D. Brennan, Sugar-Modified Silanes: Precursors for Silica Monoliths, J. Mater. Chem. 2004, 14, 1469 – 1479.

106.  F   Dina Tleugabulova, Zheng Zhang, Yang Chen, Michael A. Brook and John D. Brennan Fluorescence Anisotropy in Studies of Solute Interactions with Covalently Modified Colloidal Silica Nanoparticles, Langmuir 2004, 20, 848-854.

105.  F   Michael A. Brook, Hong Chen and Heather Sheardown, Silicone elastomers for reduced protein adsorption, Biomaterials, 2004, 25, 2273-2282.



104.  F   Frank J. LaRonde and Michael A. Brook, Allylation of aldehydes catalyzed by chiral N,N'-bis(N-methyl-2-methylene-4,5-bisphenyl-imidazole)-1,2-cyclohexane diamine rhodium (III) complexes, Can. J. Chem. 2003, 81, 1206-1212, issue dedicated to John Harrod, invited manuscript.

103.  F   Amro Ragheb, Michael A. Brook and Michael Hrynyk, Highly activated, silicone entrapped, lipase, Chem. Commun., 2003, 2314–2315.

102. F   Travis R. Besanger, Yang Chen, Anil K. Deisingh, Richard Hodgson, Wen Jin, Stanislas Mayer, Michael A. Brook and John D. Brennan, Screening of Inhibitors using Enzymes Entrapped in Sol-Gel Derived Materials, Anal. Chem. 2003, 75, 2382 – 2391.

101.  F   Brook, M. A., Laronde, F. J., Ragheb, A., Controlling Silica Surfaces Using Responsive Coupling Agents, Colloid Polym. Sci. 2003, 281, 391–400, invited manuscript.


99.    F   M. Mohamed, M. A. Brook, Allylsilane-Modified Amino Acids from the Claisen Rearrangement, Helv. Chim. Acta 2002, 85, 4165-4181 invited manuscript

98.    F   P. Zelisko, M. A. Brook, Stabilization of α-Chymotrypsin and Lysozyme Entrapped in Water-In-Silicone Oil Emulsions, Langmuir, 2002, 18, 8982-8987. 

97.    F.  Gang Hu, Frank LaRonde and Michael A. Brook, Amino acid and peptide chemistry on silicones, Silicon Chem. 2002, 1, 215–222.

96.    F. Michael A. Brook, Paul M. Zelisko, Maeghan J. Walsh and Janinne N. Crowley, Silicone-protein surfactants: stability of water-in-silicone oil emulsions, Silicon Chem. 2002, 1, 99–106.

95.    F   M. S. Eikeland, M.-B. Hägg, Michael A. Brook, M. Ottøy, A. Lindbråthen, Durability of Poly(dimethylsiloxane) when exposed to Chlorine Gas, J. Appl. Poly. Sci. A., 2002, 85, 2458-2470.

94.    F   Brook, M. A.; Ragheb, A. Oxidizable Coupling Agents: Introduction of Surface Functionality, J. Adhesion, 2002, 78, 521-541.



93.  F     Gilles Sèbe and Michael A. Brook, Hydrophobization of Wood Surfaces: Covalent Grafting of Silicone Polymers, Wood Sci. Tech. 2001, 35, 269-282.

92.  C     Mohamed, M.; Brook, M. A. Synthesis of Allylsilane-Containing Amino Acids via the Claisen Rearrangement, Tetrahedron Lett. 2001, 42, 191-193. 


91.  F     Mustafa Mohamed and Michael A. Brook, Photolysis of Tris(trimethylsilyl)silane: Trapping of Sisyl Radicals, Can. J. Chem. 2000, 78, 1357-1362.

90.  N    Bain, A., Brook, M. A.; Hazendonk, P.; Reid, D. L.; Stan, R. S. Analysis of the NMR Spectra of Some Dimethylsilanes, Magn. Res. Chem. 2000, 38, 894-895.

89.  F     Vasiliki Bartzoka, Gladys Chan and Michael A. Brook, Protein-Silicone Synergism at Liquid/Liquid Interfaces, Langmuir 2000, 16, 4589-4593.

88.  F     Sonya Balduzzi, Krista Kerr and Michael A. Brook, Alkoxyallylsilanes: Functional Protecting Groups, Tetrahedron 2000, 56, 1617-1622.

87.  F     Stradiotto, M.; Brook, M. A.; McGlinchey, M. J. The Molecular Dynamics and Reactivity of Tris(1-Indenylsilane): An NMR Spectroscopic and X-ray Crystallographic Study, J. Chem. Soc., Perkin Trans. 2, 2000, 611–618.

86. F     Stradiotto, M.; Hazendonk, P.; Bain, A. D.; Brook, M. A.; McGlinchey, M. J. Probing the Effect of Organic and Organometallic Functionalization on [1,5]-Silicon Shifts in Indenylsilanes, Organometallics, 2000, 19, 590-601.


85.  F     LaRonde, F. J.; Brook, M. A. Stereoselective Reduction of Ketones Using Extracoordinate Silicon: C2-Symmetric Ligands, Inorg. Chim. Acta 1999, 296, 208-221.

84.  C     M. R. McDermott, M. A. Brook, V. Bartzoka, Adjuvancy effect of different types of silicone gel (Letter to the Editor commenting on the paper by Naim et al. (J. Biomed. Mater. Res. 1997, 37, 5341), J. Biomed. Mater. Res. 1999, 46, 132-133.

83. F     Michael A. Brook, Christine Gottardo, Sonya Balduzzi and Mustafa Mohamed, The photolytic and hydrolytic lability of sisyl (Si(SiMe3)3) ethers, an alcohol protecting group, Tetrahedron 1999, 55, 10027-10040.

82.  F     James A. Dunn, William J. Hunks, Ralph Ruffolo, Suzie S. Rigby, Michael A. Brook, and Michael J. McGlinchey Metal Cluster Stabilized Fluorenyl, Indenyl, and Cyclopentadienyl Antiaromatic Cations: An NMR and X-ray Crystallographic Study, Organometallics 1999, 18, 3372–3382.

81.  C     Frank J. Laronde and Michael A. Brook, Stereoselective reduction of ketones by histidine-alkoxysilane complexes: The role of imidazole in nucleophilic substitution at silicon, Tetrahedron Lett. 1999, 40, 3507-3510.

80.  F     Stradiotto, M.; Brook, M. A.; McGlinchey, M. J. The Molecular Dynamics and Cycloaddition Chemistry of Tris(1-Indenyl)allylsilane: Part 1 Generation of the First Crystallographically-Characterised Tris(benzonorbonrnyl)silane, New J. Chem. 1999, 317-321.

79.  R     Vasiliki Bartzoka, Mark R. McDermott and Michael A. Brook Protein-Silicone Interactions, Advan. Mater. 1999, 11, 257-259.



78.  F     Heritage, P. L.; Underdown, B. J.; Brook, M. A.; and McDermott, M. R.; Oral Administration of Polymer-Grafted Starch Microparticles Activates Gut-Associated Lymphocytes and Primes Mice for a Subsequent Systemic Antigen Challenge, Vaccine 1998, 16, 2010-2017.

77.  N    Brook, M. A.; Urschey, J.; Stradiotto, M. Preparation of Hexacarbonyldicobalt-Complexed 1,2-Dioxa-2-Silacycloheptynes, Organometallics 1998, 17, 5342-5346.

76.  F     Ruffolo, R.; Brook, M. A.; McGlinchey, M. J. Metal-Mediated Allyl Transfers in (Alkynyl-allylsilane)Co2(CO)6 Complexes: A Synthetic and Structural Study, Organometallics 1998, 17, 4992-4996.

75.  F     McDermott, M. R.; Heritage, P. L.; Bartzoka, V.; Brook, M. A. Polymer-grafted Starch Microparticles for Oral and Nasal Immunization, Immunol. Cell Biol. 1998, 76, 256-262.

74.  C     Stradiotto, M.; Brook, M. A.; McGlinchey M. J. Can metal clusters assist silicon migrations? An NMR spectroscopic and X-ray crystallographic study, Inorg. Chem. Commun. 1998, 1, 105-108.

73.  F     Charpentier, P. A.; Hamielec, A. E.; Zhu, S.; Brook, M. A., Effect of Aluminoxane on Semi-Batch Polymerization of Ethylene Using Zirconocene Dichloride, Polymer, 1998, 39, 6501-6511.

72.  F     Vasiliki Bartzoka, Michael A. Brook, and Mark R. McDermott, Silicone-Protein Films: Establishing the Strength of the Protein-Silicone Interaction, Langmuir 1998, 14, 1892-1898.

71.  F     Vasiliki Bartzoka, Michael A. Brook, and Mark R. McDermott, Protein-Silicone Interactions: How Compatible Are The Two Species? Langmuir 1998, 14, 1887-1891.

70.  F     Howard A. Ketelson, Robert Pelton, and Michael A. Brook, Surface and Colloidal Properties of Hydrosilane Modified Stöber Silica, Colloids and Surfaces A 1998, 132, 229-239.

69.  F     Heritage, P. L.; Brook, M. A.; Underdown, B. J. and McDermott, M. R.; Intranasal Immunization with Polymer-Grafted Microparticles Activates the Nasal-Associated Lymphoid Tissue and Draining Lymph Nodes, Immunology 1998, 93, 249-256.

68.  F     Michael A. Brook and Tomislav M. Stefanac, Hydrovinylsilanes in Sequential Reactions: A Route to Graft Copolymers [1], Heteroatom Chem. 1998, 9, 241-251.

67.  F      Le Roux, C.; Yang, H.; Wenzel, S.; Grigoras, S.;  Brook, M. A. Using “Anhydrous” Hydrolysis to Favor Formation of Hexamethylcyclotrisiloxane from Dimethyldichlorosilane, Organometallics 1998, 17, 556-564.



66.  F     Paul A. Charpentier, Shiping Zhu, Archie E. Hamielec and Michael A. Brook, Continuous Solution Polymerization of Ethylene Using Metallocene Catalyst System, Zirconcene Dichloride/Methylaluminoxane/Trimethylaluminum, Ind. Chem. Eng. Res. 1997, 36, 5074-5082. DOI: 10.1021/ie9704152

65.  F    Ralph Ruffolo, Sabine Kainz, Hari K. Gupta, Michael A. Brook, and Michael J. McGlinchey, A Synthetic and Structural Study on Metal Cluster Complexes of Allyl-Alkynyl-Silanes: Does Protonation Lead to Metal-Stabilized Silyl Cations?, J. Organomet. Chem. 1997, 547, 217-226.

64.  F     Lau, W. W. Y.; Finlayson, J.; Dickson, J. M.; Jiang, J.; Brook, M. A. Pervaporation performance of oligosilylstyrene-polydimethylsiloxane membrane for separation of organics from water. J. Membr. Sci. 1997, 134, 209-217.

63.  F     Michael A. Brook, Jianxiong Jiang, Philippa Heritage, Brian Underdown and Mark R. McDermott, Silicone-modified starch/protein microparticles: protecting biopolymers with a hydrophobic coating, Colloids and Surfaces B: Biointerfaces 1997, 9, 285-295.

62.  F     Michael A. Brook, Jianxiong Jiang, Philippa Heritage, Vasiliki Bartzoka, Brian Underdown and Mark R. McDermott, The Silicone-Protein Interaction at the Interface between a Functional Silicone and a Protein/Starch Microparticle, Langmuir 1997, 13, 6279-6286.

61.  F.    Stradiotto, M.; Hughes, D. W.; Bain, A. D.; Brook, M. A.; McGlinchey, M. J., The Fluxional Character of (h5-C5H5)Fe(CO)2(h1-C9H7): Evidence for the [4+2] Cycloaddition of a Metal-Substituted Isoindene with Tetracyanoethylene, Organometallics 1997, 16, 5563-5568.

60. F     T. Kuhnen, M. Stradiotto, R. Ruffolo, D. Ulbrich, M. J. McGlinchey and Michael A. Brook, Oligo(alkynylsilanes): Templates for Organometallic Polymers, Organometallics 1997, 16, 5048-5057.

59.  F     T. Kuhnen, M. Stradiotto, R. Ruffolo, D. Ulbrich, M. J. McGlinchey and Michael A. Brook, Using Hydrosilylation To Assemble Organometallic Polymers Containing Combinations of Silicon-Based Functional Groups, Organometallics 1997, 16, 5042-5047.

58. C     Brook M. A.; Gottardo, C.; Balduzzi, S.; Mustafa, M. The Sisyl (tris(Trimethylsilyl)sil yl) Group: A Fluoride Resistant, Photolabile Alcohol Protecting Group, Tetrahedron Lett. 1997, 38, 6997-7000.

57   F     Michael A. Brook, Howard A. M. Ketelson, F. LaRonde and Robert H. Pelton, Pt0 compounds bound in a silsesquioxane layer: active hydrosilation catalysts protected by the gel, Inorg. Chim. Acta 1997, 264, 125-135, (invited manuscript).

56.  C     Mark J. Stradiotto, Grant Crowe, Ralph Ruffolo and Michael A. Brook, 1-Styrylsilatrane, Acta Cryst. 1997, C53, 637-639.

55.  F     Stephen Urquhart, Cássia C. Turci, Tolek Tyliszczak, Michael A. Brook and Adam P. Hitchcock, Core Excitation Spectroscopy of Phenyl- and Methyl-Substituted Silanol, Disiloxane and Disilane Compounds: Evidence for π-Delocalization Across the Si-CPhenyl Bond, Organometallics, 1997, 16, 2080-2088.


54. F    Yeom, C.-K.; Dickson, J. M.; Brook, M. A. A Characterization of PDMS Pervaporation Membranes for the Removal of Trace Organic from Water, Korean. J. Chem. Eng. 1996, 13, 482-488.Mark Stradiotto,

53. F     Suzie S. Rigby, Donald W. Hughes, Michael A. Brook, Alex D. Bain and Michael J. McGlinchey, Multidimensional NMR Study of  Tris(indenyl)methylsilane: Molecular Dynamics Mapped onto a Hypercube, Organometallics. 1996, 15, 5645-5652.

52.  F     Michael A. Brook, Bjørn Ramacher, Carol Dallaire, Hari K. Gupta, Dagmar Ulbrich and Ralph Ruffolo, Steric control in the formation of Co2(CO)6-alkyne complexes from Group 14 tetraalkynes and their reactions with acid, Inorg. Chim. Acta, 1996, 250, 49-57, invited manuscript.

51.  F     Michael J. Roth, Michael A. Brook and Helen B. Penny, Hydrosilane Cleavage Reactions Accelerated By Tartaric Acid and Dimethyl Sulfoxide, J. Organomet. Chem., 1996, 521, 65-74, invited manuscript dedicated to Robert Corriu.

50.  F     Christopher Roos, Graham A. McGibbon and Michael A. Brook, The thermolysis of ε-halodisilanes: a preference for 1,2-Si Si → O rearrangement or Si—O cleavage over Si=O bond formation, Can. J. Chem. 1996, 74, 1470-1479.

49.  C     Michael A. Brook, Howard A. M. Ketelson, Robert H. Pelton, and Yew. M. Heng, Hydridosilsesquioxane Modified Silica-Supported Platinum Nanoparticles, Chem. Mater. 1996, 8, 2195-2199.

48.  F     Tomislav M. Stefanac, Michael A. Brook, and R. Stan, Radical Reactivity of Hydrovinylsilanes: Homooligomers, Macromolecules 1996, 29, 4549-4555.

47.  F     Wan Zhang, John A. Stone, Michael A. Brook and Graham A. McGibbon, Stabilization of Vinyl Cations by b-Silicon: A Quantitative Mass Spectrometric Study, J. Am. Chem. Soc. 1996, 118, 5764-5771.

46.  F     Howard A. Ketelson, M. A. Brook and R. H. Pelton, Colloidal Stability of Stöber Silica in Acetone-Water Mixtures, J. Colloid Interface Sci. 1996, 179, 600-607.

45.  F     R. Pelton, Huining Xiao, Michael A. Brook and Archie Hamielec, Flocculation of polystyrene latex with mixtures of poly(p-vinyl phenol) and poly(ethylene oxide), Langmuir, 1996, 12, 5756-5762.

44.  F     P.L. Heritage, L. M. Loomes, J. Jiang, M.A. Brook, B.J. Underdown and M.R. McDermott, Novel Polymer-Grafted Starch Microparticles for Mucosal Delivery of Vaccines, Immunology, 1996, 88, 162-168.

43.  F     Howard A. Ketelson, M. A. Brook and R.H. Pelton, Colloidal Stability of Stöber Silica in Acetone, Langmuir, 1996, 12, 1134-1140.

42.  F     Michael A. Brook and Courtney Henry, Competitive Acylation Of Arylstyrylsilanes: Controlling Silanucleophile Reactivity, Tetrahedron 1996, 52, 861-868



41. F      Michael A. Brook, Thomas Sebastian, Peter Hülser, Ralf Jüschke, Stefan Wenzel, Jennifer A. Townsend and Patricia R. Falletta, b-Trichlorosilylstryene Oligomers, Can. J. Chem., 1995, 73, 1794-1802.

40.  F     Michael A. Brook, Courtney Henry, Elizabeth Jefferson, Ralf Jüschke, Thomas Sebastian, Mirek Tomaszewski and Stefan Wenzel, Electrophilic Additions to Styrylsilanes: The Effect of Changing the Ligands on Silicon, issue dedicated to Raymond Calas, Bull. Soc. Chim. Fr. 1995, 132, 559-568, invited manuscript.

39. F     H. A. M. Ketelson, Michael A. Brook, and Robert H. Pelton, Colloidal Silica Bearing Hydrosilane Groups, Chem. Mater. 1995, 7, 1376-1383.

38.  F     Howard A.M. Ketelson, Michael A. Brook and Robert H. Pelton, Sterically stabilized silica colloids: Radical grafting of poly(methyl methacrylate) and Hydrosilylative grafting of silicones to Functionalized Silica, Polym. Adv. Technol. 1995, 6, 335-344.

37.  F     Ralph Ruffolo, Andreas Decken, Luc Girard, Hari K. Gupta, Michael A. Brook and Michael J. McGlinchey, Toward Metal-Stabilized Silylium Cations: An EHMO Study of [(HCºC-SiH2)Co2(CO)6]+ and X-ray Crystal Structures of (Me3CºCSiPh2H)Mo2(CO)4Cp2 and [(Me3SiCºCSiMe2)Co2(CO)6]2, Organometallics 1994, 13, 4328-4335.

36.  F     Courtney Henry and Michael A. Brook, Proton Additions to Silylstyrenes: Overcoming the Prediliction for Protiodesilylation, Tetrahedron, 1994, 50, 11379-11390.

35.  F     Jianxiong Jiang, Michael A. Brook and J. M. Dickson, Substitution reactions at silicon under strongly acidic conditions: Ligand metathesis between methyltrichlorosilane and octamethylcyclotetrasiloxane, Heteroatom Chemistry, 1994, 5, 275-285.

34.  F     Courtney Henry and Michael A. Brook, Electrophilic addition to styrylsilanes: Sequential carbon-carbon bond forming reactions, Inorg, Chim. Acta 1994, 220, 145-154.

33.  C     Michael A. Brook, Henk Hiemstra and Grant Crowe, Allyldimethylsilyl Triflate: A Self-Catalyzed Silyl Nucleophile, Can. J. Chem., 1994, 72, 264-267.

32.  C     Michael A. Brook, Daniel Chau, Michael J. Roth, Weifeng Yu and Helen Penny, The Surprising Reactivity of Alkoxyhydrosilanes Towards a-Hydroxy Carboxylic Acids, Organometallics, 1994, 13, 750-752.

31.  F     Carol Dallaire, Michael A. Brook, Alex D. Bain, Christopher S. Frampton and James F. Britten, Tetrakis[(Trimethylsilyl)Ethynyl] Group 14 Metal Derivatives: An Examination Of The Electronic Interaction Between Two Group 14 Metals Connected By An Acetylene Wire, Can. J. Chem. 1993 71, 1676-1683.

30.  F     Eric C. Roos, M. Carmina López, Michael A. Brook, Henk Hiemstra, W. Nico Speckamp, Bernard Kaptein, Johan Kamphuis, and Hans E. Schoemaker, Synthesis of a-Substituted a-Amino Acids via Cationic Intermediates, J. Org. Chem. 1993, 58, 3259-3268.

29.  F     Carol Dallaire and Michael A. Brook, The b-Effect with Vinyl Cations: A Kinetic Study of the Protiodemetallation of Silyl, Germyl and Stannyl Alkynes, Organometallics 1993, 12, 2332-2338.

28.  N    Michael A. Brook, Pankaj Modi and James M. Dickson, Silicon Functionalized Styrene Polymers, Macromolecules 1993, 26, 2624-2627.

27.  F     Michael A. Brook, Courtney Henry, Ralf Jueschke and Pankaj Modi, Balancing Leaving Group Ability and the b-Effect: Exploring the Synthetic Utility of Chlorosilyl Groups, Synlett 1993, 2, 97-104.

26.  C     Graham A. McGibbon, Michael A. Brook and Johan K. Terlouw, Stabilization energies for α- and β-silyl substituents on vinyl cations determined using mass spectrometric techniques, J. Chem. Soc., Chem. Commun. 1992, 360-362.

25.  F     Robert H. Pelton, Andrea Osterroth and Michael A. Brook, Silicone Stabilized Poly(methyl methacrylate) Nonaqueous Latex.  2  Flocculation By Degradation of the Steric Layer, J. Colloid Interface Sci. 1991, 147, 523-530.

24.  C     Michael A. Brook, Thomas Sebastian, Ralf Jueschke and Carol Dallaire, The Diastereoselective Addition of Carbon Electrophiles to Styrylsilanes:  The Dimerization of b-E-Halosilylstyrenes, J. Org. Chem. 1991, 56, 2273-2274.

23.  C     Michael A. Brook and Carol Dallaire, Relative magnitude of the .beta.-effect of silyl, germyl, and stannyl groups in the stabilization of vinyl cations, Organometallics 1990, 9, 2873-2875.

22.  F     Michael A. Brook and Axel Neuy, The b-Effect: Changing the Ligands on Silicon, J. Org. Chem. 1990, 55, 3609-3616.

21.  F     Robert

H. Pelton, Andrea Osterroth and Michael A. Brook, Silicone Stabilized Poly(methyl methacrylate) Nonaqueous Latexes: I. Preparation and characterization, J. Colloid Interface Sci. 1990, 137, 120-127.


20.  F     Albert Elmer and Michael A. Brook, Draw2D, Draw3D: MOPAC 2- and 3-Dimensional Graphical Output Written Using the PHIGS Graphics Standard, Tetrahedron Computer Method. 1989, 2, 223-232.

19.  C     Michael A. Brook, Peter Hülser and Thomas Sebastian, Oligo(trichlorosilyl)styrenes: Highly Functionalized Silicone Precurors, Macromolecules 1989, 22, 3814-3816.

18.  C     Michael A. Brook, Mahmud A. Hadi and Axel Neuy, An Examination of the b-Effect in an Addition Reaction with Different Ligands on Silicon, J. Chem. Soc., Chem. Commun. 1989, 957-958.

17.  C     Michael A. Brook, Christina H. Kremers, Thomas Sebastian and Weifeng Yu, A Novel Glycol-Silicone Polymer, J. Poly. Sci., Polymer Lett. 1989, 27, 229-234.

16.  C     Michael A. Brook, Romolo Faggiani, C.J.L. Lock and Dieter Seebach, u,l-4a,5,6,7,8,8a-Hexahydro-4-phenyl-8a-(trimethylsiloxy)-4H-1,2-benzoxazine-2-oxide, Acta Cryst. 1988, C44, 1981-1984.

15.  C     Pierre G. Potvin, Patrick C.C. Kwong and Michael A. Brook, Solution Structures of Sharpless Epoxidation Catalysts, J. Chem. Soc., Chem. Commun., 1988, 773-775.

14.  F     Nick Henry Werstiuk, Michael A. Brook and Peter Hülser, Thermolysis of Trimethylsilyl Esters: An Ultraviolet Photoelectron Spectroscopy Study, Can. J. Chem. 1988, 66, 1430-1439.

13.  C     Michael A. Brook and Jahangir, The Activation of Imines to  Nucleophilic Attack by Grignard Reagents, Synth. Commun. 1988, 18, 893-898.

12.  F     Jahangir, Michael A. Brook, David B. MacLean and Herbert H. Holland, A New Route to the Indolopyridonaphthyridine Ring System: Synthesis of N-Benzyl-13b,14-dihydronaucléfine and N-Benzyl-13b,14-dihydroangustine, Tetrahedron 1987, 43, 5761-5768.

11.  F     Jahangir, M.A. Brook, D.B. MacLean, and H. L. Holland, 8H-Isoquino[2,1-b][2,7]naphthyridine-8-ones: synthesis of the Alangium alkaloids, alangimaridine and alangimarine, Can. J. Chem. 1987, 65, 2362-2368.

10.  R     Michael A. Brook, The Nomenclature of Relative Stereochemistry:  Choosing Between likes and preferences, J. Chem. Educ. 1987, 64, 218-220.

9.    C     Michael A. Brook and Dieter Seebach, Cyclic Nitronates from the Diastereoselective Addition of 1-Trimethylsilyloxycyclohexene to Nitroolefins.  - Starting Materials for Stereoselective Henry Reactions and 1,3-Dipolar Cycloadditions, Can. J. Chem. 1987, 65, 836-850

8.    F     Jahangir, D.B. MacLean, M.A. Brook and H.L. Holland, Activated Imines as Carbon Electrophiles: Applications in Alkaloid Synthesis, J. Chem. Soc., Chem. Commun. 1986, 1608-1609.

7.    C     T.H. Chan and M.A. Brook, INEPT-29Si NMR Study of a TiCl4-Mediated Reaction of an Enol Silyl Ether, Tetrahedron Lett. 1985, 2943-2947.

6.    C     Dieter Seebach and Michael A. Brook, Reversed Stereochemical Course of the Michael Addition of Cyclohexanone to B-Nitrostyrenes by Using 1-Trimethylsilyloxycyclohexene /Dichlorodiisopropoxytitanium-Preliminary Communication, Helv. Chim. Acta 1985, 68, 319-324.

5.    C     S.D. Lee, Michael A. Brook and T.H. Chan, Conversion of Primary Amides into Active Acylating Agents via Acylpyrroles, Tetrahedron Lett. 1983, 1569-1572.

4.    F     P. Brownbridge, T.H. Chan, M.A. Brook and G.J. Kang, Chemistry of Silyl Enol Ethers.  A General Synthesis of 3-Hydroxyhomophthalates and a Biomimetic Synthesis of Sclerin, Can. J. Chem. 1983, 61, 688-693.

3.    C     T. H. Chan, Michael A. Brook and T. Chaly, A Simple Procedure for the Acetalization of Carbonyl Compounds, Synthesis 1983, 203-205.

2.    C     Michael A. Brook and T.H. Chan, A Simple Procedure for the Esterification of Carboxylic Acids, Synthesis 1983, 201-203.

1.    F     M.A. Nazar, W.H. Rapson, M.A. Brook, S. May and J. Tarhanen, Mutagenic Reaction Products of the Aqueous Chlorination of Catechol, Mutat. Res. 1981, 89, 45-55.

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